{"@context":"http://iiif.io/api/presentation/2/context.json","@type":"sc:Manifest","@id":"https://iiif.quartexcollections.com/wesleyan/iiif/8cb95369-662e-4b90-bbd8-8a00a4b0fdd8/manifest","label":"m2023-s985","metadata":[{"label":"Title","value":"Synthesis and polymerization of strained epoxidized five- and six-membered rings"},{"label":"Subject","value":["Polymerization"]},{"label":"Rights","value":["In Copyright"]},{"label":"Repository","value":["University Archives"]},{"label":"Language","value":["English"]},{"label":"Item Information","value":"<a href=\"https://onesearch.wesleyan.edu/permalink/01CTW_WU/12cbh08/alma9933182475503768\" target=\"_blank\">M2023 S985</a>"},{"label":"Held By","value":"Wesleyan University Library, Wesleyan University, Middletown, CT, USA"},{"label":"Group","value":["Theses & Dissertations"]},{"label":"Name(s)","value":["Sylvester, Kyle R. (creator)"]},{"label":"Administrative Note","value":"Node ID: 33997<br>Author Contact: ksylvester@wesleyan.edu<br>Local Identifier: 1651"},{"label":"Author-supplied Keywords","value":["Synthesis","Polymerization","Strain epoxidized rings"]},{"label":"Degree","value":["Master of Arts"]},{"label":"Description","value":"<p>Sustainable polymers are at the forefront of the polymer science community due to their importance in combating the global plastic accumulation issue. While most research on sustainable polymers focuses on replacing fossil fuel-derived materials with new alternatives, other areas need to be investigated in more depth. Specifically, the development of new classes of monomers and strategies for the depolymerization of polymers. Ring-opening metathesis polymerization (ROMP), used with living polymerizations, is a technique that can synthesize polymers with high molecular weights and narrow molecular weight distributions. Typically, ROMP is carried out with the use of highly strained monomers. \n\tWe have investigated a five-membered (cyclopentadiene monoepoxide monomer) and a six-membered (anti-benzene monomer) epoxidized ring; both of which have what is considered moderate ring strain. While the six-membered ring presented issues in its polymerization process, the five-membered ring has been purely synthesized and fully polymerized amongst some obstacles. We have proven that this polymer can undergo post-polymerization modifications, a technique that can functionalize the side chains of a polymer backbone differentiating its properties for further uses. We hope that these monomers and their polymers can effectively be used in amphiphilic block copolymer systems; eventually leading to the assembly of micelles for drug delivery systems and other biological processes.</p>"},{"label":"Digital Identifier","value":"m2023-s985"},{"label":"Thesis Advisor(s)","value":["Elling, Ben"]},{"label":"Digital Object Identifier (DOI)","value":"https://doi.org/10.14418/wes01.2.381"},{"label":"Discipline","value":["Chemistry"]},{"label":"Date","value":"May 4, 2023"},{"label":"EDTF Date","value":"D:00 M:00 Y:2023"},{"label":"Extent","value":"65 pages : illustrations, charts ; 28 cm"},{"label":"File Format","value":["application/pdf"]},{"label":"Genre","value":["masters theses"]},{"label":"Digital Origin","value":["born digital"]},{"label":"Type","value":["Text"]}],"description":"Synthesis and polymerization of strained epoxidized five- and six-membered 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