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(creator)"]},{"label":"Administrative Note","value":"Drupal Node ID: 56219<br>author email: cordonez@wesleyan.edu<br>old filename: 1249_384809"},{"label":"Degree","value":["Bachelor of Arts with Departmental Honors"]},{"label":"Description","value":"<p>The origin of Earth's water remains one of the most fundamental questions in planetary science. Unequilibrated EH3 Enstatite Chondrites (EC) have emerged as potential contributors to Earth's water inventory due to oxygen isotopic values similar to those of Earth and due to structurally bound hydroxyl (OH) in anhydrous mineral phases, like pyroxene and mesostases. This study introduces a new high-resolution method for quantifying trace water in ECs by coupling a Secondary Ion Mass Spectrometry (SIMS) with a third generation Stacked CMOS Active Pixel Sensor (SCAPS) imaging sensor. Two unequilibrated EH3 enstatite chondrite samples from the Almahata Sitta meteorite fall were analyzed using this technique.</p><p>A series of SIMS/SCAPS spot analyses and calibration curves were derived from well-characterized pyroxene standards (5—259 ppm H2O) and Suprasil 3002 glass (1 ppm H2O). SIMS/SCAPS analysis revealed 11 consistent measurements of enstatite grains averaging 4.67 ¬±.34 ppm H2O and only one measurement in mesostases containing approximately 195.87 ¬±19 ppm H2O.</p><p>Analytical trade-offs between spatial resolution and beam size were evaluated, highlighting the importance of beam optimization. Furthermore, this study emphasizes and identifies the widespread contamination of terrestrial water within the primary and secondary phases. It also emphasizes the importance of distinguishing terrestrial water from endogenous water that may not be identifiable with other measurement techniques. Our findings contradict the growing hypothesis that ECs are inherently hydrated and may have played a significant role in the delivery of water to Earth. The SIMS/SCAPS technique provides a robust framework for the spatially resolved quantification of trace water in meteorites and has broad implications for understanding volatile inventories in the early Solar System.</p>"},{"label":"Group","value":["Theses & Dissertations"]},{"label":"Digital Origin","value":["born digital"]},{"label":"Discipline","value":["Earth and Environmental Sciences"]},{"label":"Date","value":"April 15, 2025"},{"label":"EDTF Date","value":"D:00 M:00 Y:2025"},{"label":"File Format","value":["application/pdf"]},{"label":"Digital Object Identifier (DOI)","value":"https://doi.org/10.14418/wes01.1.3167"},{"label":"Type","value":["Text"]}],"description":"New technique for measuring water: Almahata Sitta EH3 enstatite 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