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We explore the phase behavior and structure of a model for NP functionalized with between 3 and 6 short ssDNA through simulations, allowing us to examine both the role of the number of attached strands (valency) and their relative orientations. We find that 3 to 5-functionalized NP form amorphous systems, with 4 and 5-functionalized NP constructing an unusual multitude of liquid phases, or polyamorphism, through interpenetration of networks. The 6-functionalized NP with octahedral symmetry form at least six crystalline structures, consisting of up to six interpenetrating simple cubic lattices. The crystallization dynamics of the 6-functionalized system follows the conventional two-step pathway, demonstrating that such mechanism applies to our NP system with complex interactions.</p>"},{"label":"Degree","value":["Bachelor of Arts with Departmental Honors"]},{"label":"Author-supplied Keywords","value":["Nanoparticle","DNA","Self-Assembly"]},{"label":"Administrative Note","value":"2010<br>Old URL: https://wesscholar.wesleyan.edu/etd_hon_theses/572<br>Drupal Node ID: 22745<br>author email: wdai@wesleyan.edu<br>old filename: dai_wei_2011_183_572<br>PID: ir:1528"},{"label":"Name(s)","value":["Dai, Wei (creator)"]},{"label":"Discipline","value":["Physics"]},{"label":"Type","value":["Text"]}],"description":"Effect of valency on the dynamics and thermodynamics of DNA-linked nanoparticles 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