{"@context":"http://iiif.io/api/presentation/2/context.json","@type":"sc:Manifest","@id":"https://iiif.quartexcollections.com/wesleyan/iiif/679dcc4d-06f7-4bdd-9ca8-9991c0841aff/manifest","label":"m2020-f199","metadata":[{"label":"Title","value":"Structure and dynamics of polymer/star-polymer composites"},{"label":"Subject","value":["Star-branched polymers","Polymers"]},{"label":"Rights","value":["In Copyright"]},{"label":"Repository","value":["University Archives"]},{"label":"Language","value":["English"]},{"label":"Item Information","value":"<a href=\"https://onesearch.wesleyan.edu/permalink/01CTW_WU/12cbh08/alma9932727859003768\" target=\"_blank\">M2020 F199</a>"},{"label":"Held By","value":"Wesleyan University Library, Wesleyan University, Middletown, CT, USA"},{"label":"Group","value":["Theses & Dissertations"]},{"label":"Name(s)","value":["Fan, Jinpeng (creator)"]},{"label":"Administrative Note","value":"Node ID: 17101<br>Administrative Notes: Access was restricted until 2021-04-15.<br>Author Contact: jfan@wesleyan.edu<br>Local Identifier: 462<br>PID: ir:2800"},{"label":"Author-supplied Keywords","value":["Composite","Star polymer","Polymer","Nanoparticles"]},{"label":"Degree","value":["Master of Arts"]},{"label":"Description","value":"<p>Nanoparticles (NP) are versatile building blocks to create tunable particle superstructures and polymer nanocomposites with customizable properties. NP are topologically similar to star polymers with large numbers of arms, which exhibit soft-colloidal behavior. While polymer composites with NP have been explored recently, comparatively little is known about composites consisting of star polymers and chain polymers, or star polymers in polymer thin films. We investigate how both the number of arms and molecular mass affect the morphology of self-assembled structures in both a bulk polymer material and an ultra-thin polymer film. Additionally, we study how star polymers affect the glass transition of these composites and films, and compare our findings with those of polymer-NP composites. In doing so, we also examine how the polymer/star-polymer interaction strength affects the structure and dynamics in the matrix and film, and how this potentially relates to changes in the mechanical and rheological properties of the material. We find that the effect of star polymers on dynamical and mechanical properties of the composites is small compared to that of nanoparticles, despite the large degree of interdigitation between polymer matrix and star polymers with large number of arms when polymer/star-polymer interaction is strong.</p>"},{"label":"Digital Identifier","value":"m2020-f199"},{"label":"Thesis Advisor(s)","value":["Starr, Francis W."]},{"label":"Digital Object Identifier (DOI)","value":"https://doi.org/10.14418/wes01.2.285"},{"label":"Discipline","value":["Physics"]},{"label":"Date","value":"May 8, 2020"},{"label":"EDTF Date","value":"D:00 M:00 Y:2020"},{"label":"Extent","value":"v, 47 leaves : illustrations ; 29 cm"},{"label":"File Format","value":["application/pdf"]},{"label":"Genre","value":["masters theses"]},{"label":"Digital Origin","value":["born digital"]},{"label":"Type","value":["Text"]}],"description":"Structure and dynamics of polymer/star-polymer 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