{"@context":"http://iiif.io/api/presentation/2/context.json","@type":"sc:Manifest","@id":"https://iiif.quartexcollections.com/portland/iiif/79f4b23e-edbe-4649-a80e-8346094f1e0f/manifest","label":"Polymeric (diphenylphosphinato)tetrahydro-furanlithium","metadata":[{"label":"Title","value":"Polymeric (diphenylphosphinato)tetrahydro-furanlithium"},{"label":"Collection","value":["Chemistry Faculty Publications"]},{"label":"Relation","value":"chm"},{"label":"Author","value":"Natcharee Kongprakaiwoot, Rudy L. Luck, Eugenijus Urnezius"},{"label":"Journal Title","value":"Acta Crystallographica Section E"},{"label":"Abstract","value":"In the title compound, [Li(C12H10O2P)(C4H8O)]n, the O atoms of adjacent and bridging diphenylphosphinate ligands and that from a tetrahydrofuran (thf) molecule are arranged in a tetrahedral manner around the Li atoms, resulting in a one-dimensional array (parallel to the a axis) of alternate eight-membered and rectangular planar four-membered rings [the two Li-O distances are 1.962 (6) and 1.991 (6) Å, and the Li-O-Li and O-Li-O angles are 88.3 (2) and 91.7 (2)°, respectively]. The Li-O distances for the O atoms of the phosphinate ligand are 1.992 (6) (for the -O atom) and 1.897 (6) Å, and the distance from Li to the O atom of the thf ligand is 2.028 (6) Å."},{"label":"DOI","value":"10.1107/S1600536802020986"},{"label":"Volume","value":"58"},{"label":"Issue","value":"12"},{"label":"Publication Date","value":"D:00 M:12 Y:2002"},{"label":"Publication Information","value":"Copyright 2002 International Union of Crystallography. The original published version of this article may be found at http://dx.doi.org/10.1107/S1600536802020986."}],"description":"Polymeric (diphenylphosphinato)tetrahydro-furanlithium","sequences":[{"@type":"sc:Sequence","canvases":[{"@id":"https://iiif.quartexcollections.com/portland/iiif/79f4b23e-edbe-4649-a80e-8346094f1e0f/canvas/_1","@type":"sc:Canvas","label":"Polymeric (diphenylphosphinato)tetrahydro-furanlithium-2","height":1655,"width":1271,"images":[{"@type":"oa:Annotation","motivation":"sc:painting","resource":{"@id":"https://iiif.quartexcollections.com/portland/iiif/83f14adb-d83b-4154-9298-1492ec261395/full/full/0/default.jpg","@type":"dctypes:Image","format":"image/jpeg","service":{"@context":"http://iiif.io/api/image/2/context.json","@id":"https://iiif.quartexcollections.com/portland/iiif/83f14adb-d83b-4154-9298-1492ec261395","profile":"http://iiif.io/api/image/2/level2.json","tiles":[{"width":512,"scaleFactors":[1,2,4]}]},"height":1655,"width":1271},"on":"https://iiif.quartexcollections.com/portland/iiif/79f4b23e-edbe-4649-a80e-8346094f1e0f/canvas/_1","metadata":[]}],"thumbnail":{"@id":"https://iiif.quartexcollections.com/portland/iiif/83f14adb-d83b-4154-9298-1492ec261395/full/500,500/0/default.jpg","@type":"dctypes:Image","height":500,"width":500}},{"@id":"https://iiif.quartexcollections.com/portland/iiif/79f4b23e-edbe-4649-a80e-8346094f1e0f/canvas/_2","@type":"sc:Canvas","label":"Polymeric (diphenylphosphinato)tetrahydro-furanlithium-3","height":1655,"width":1271,"images":[{"@type":"oa:Annotation","motivation":"sc:painting","resource":{"@id":"https://iiif.quartexcollections.com/portland/iiif/5da0d777-9a1e-4d9f-9b9c-f97b4a6f3150/full/full/0/default.jpg","@type":"dctypes:Image","format":"image/jpeg","service":{"@context":"http://iiif.io/api/image/2/context.json","@id":"https://iiif.quartexcollections.com/portland/iiif/5da0d777-9a1e-4d9f-9b9c-f97b4a6f3150","profile":"http://iiif.io/api/image/2/level2.json"},"height":1655,"width":1271},"on":"https://iiif.quartexcollections.com/portland/iiif/79f4b23e-edbe-4649-a80e-8346094f1e0f/canvas/_2","metadata":[]}],"thumbnail":{"@id":"https://iiif.quartexcollections.com/portland/iiif/5da0d777-9a1e-4d9f-9b9c-f97b4a6f3150/full/500,500/0/default.jpg","@type":"dctypes:Image","height":500,"width":500}}]}],"thumbnail":"https://iiif.quartexcollections.com/portland/iiif/83f14adb-d83b-4154-9298-1492ec261395/full/300,300/0/default.jpg","logo":"https://iiif.quartexcollections.com/portland/iiif/logo"}